Natural rubber is a polymer of:

Styrene

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Ethyne

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Butadiene

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Isoprene

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Solution

The correct option is D Isoprene
The monomer of natural rubber is isoprene.
Polyisoprene, a polymer of isoprene $C_{5} H_{8}$ is the primary chemical constituent of natural rubber.
The structure of Isoprene is

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