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Question

NH3 gas is liquefied more easily than N2, hence:

A
vander Waal's constants 'a' and 'b' of NH3>N2
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B
vander Waal's constants 'a' and 'b' of NH3<N2
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C
Both A and B
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D
None of these
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Solution

The correct option is A Both A and B
'a' represents attraction between molecules.
'b' represents size\volume of the molecule.
For NH3 gas to be more liquifiedable than N2, one of the following must hold.
i) aNH3>aN2
ii) bNH3<bN2
iii) Both (i) and (ii) should hold simultaneously.

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