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Question

NH4HS(s)NH3(g)+H2S(g)
The equilibrium pressure at 25oC is 0.660atm. What is Kp for the reaction?

A
0.109
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B
0.218
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C
1.89
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D
2.18
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Solution

The correct option is A 0.109
Kp = 0.11 Atm2
The solid reactant has zero partial pressure
So Kp = PNH3 . PH2S
Here P denotes the partial pressure of each gas.
PNH3 + PH2S =0.660 atm
PNH3 = 0.33 atm
PH2S = 0.33 atm
So now they are in 1 : 1 ratio
So Kp = 0.109 atm2



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