NiCl 2- KCN excess - A cyano complex NiCl 2- conc-HClexcess - B Chloro complexThe hybridisation of A and B are-A- dsp 2- sp 3B- dsp 2- dsp 2C- sp 3 d 2- d 2 sp 3D- sp 3- sp 3

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VBT Tetrahedral vs Square Planar

NiCl 2+ KCN e...

Question

$N i C l_{2} + K C N (e x c e s s) \to A (c y a n o c o m p l e x)$
$N i C l_{2} + c o n c . H C l (e x c e s s) \to B (C h l o r o c o m p l e x)$
The hybridisation of A and B are:

d s p^{2}, s p^{3}

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s p^{3}, s p^{3}

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d s p^{2}, d s p^{2}

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s p^{3} d^{2}, d^{2} s p^{3}

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Solution

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N i C l_{2} + K C N (e x c e s s) \to A (c y a n o c o m p l e x)

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N i C l_{2} + K C N (e x c e s s) \to A (c y a n o c o m p l e x)

N i C l_{2} + c o n c . H C l (e x c e s s) \to B (C h l o r o c o m p l e x)

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