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Question

Nitration of nitrobenzene at 125oC with mixed acids gives:

A
meta-dinitrobenzene
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B
ortho-dinitrobenzene
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C
para-dinitrobenzene
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D
1,3,5-trinitro benzene
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Solution

The correct option is A meta-dinitrobenzene

1,3-Dinitrobenzene is accessible by nitration of nitrobenzene. The reaction proceeds under acid catalysis using sulfuric acid. The directing effect of the nitro group of nitrobenzene leads to 93% of the product resulting from nitration at the meta-position. The ortho- and para-products occur in only 6% and 1%, respectively.

Dinitrobenzenes are chemical compounds composed of a benzene ring and two nitro group (NO2) substituent’s. The three possible arrangements of the nitro groups afford three isomers, 1,2-dinitrobenzene, 1,3-dinitrobenzene, and 1,4-dinitrobenzene. Each isomer has the chemical formula C6H4N2O4 and a molar mass of about 168.11 g/mol. 1,3-Dinitrobenzene is the most common isomer and it is used in the manufacture of explosives.


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