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Question

Nitro compounds can be reduced with active metals such as Fe, Sn, Zn etc. Which of the following is true statement?

A
The reduction with fe/ HCl is preferred.
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B
The reduction with Sn/ HCl is preferred.
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C
The reduction with Zn / HCl is preferred.
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D
The reduction with Sn/HCl and Zn/ HCl is preferred.
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Solution

The correct option is A The reduction with fe/ HCl is preferred.
The reduction with fe/ HCl is preferred. FeCl2 formed gets hydrolysed to release HCl. Hence, only a small amount of HCl is needed to initiate the reaction.

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