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Question

Nitrogen and hydrogen are added to a 5 litre flask under pressure. The flask was sealed and heated. The equilibrium mixture contained 19.0g of ammonia, 0.16g of hydrogen and 3.4g of nitrogen. Calculate the equilibrium constant, Kc of the reaction:
N2(g)+3H2(g)2NH3(g)

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Solution

Nitrogen and hydrogen are added to a 5 litre flask under pressure. The flask was sealed and heated. The equilibrium mixture contained 19.0g of ammonia, 0.16g of hydrogen and 3.4g of nitrogen.
N2(g)+3H2(g)2NH3(g)
The molecular weights of nitrogen, hdrogen and ammonia are 28 g/mol, 2 g/mole and 17 g/mole respectively.
[N2]= 3.4 g 28 g/mol × 5 L = 0.02429 M
[H2]= 0.16 g 2 g/mol × 5 L = 0.016 M
[NH3]= 19.0 g 17 g/mol × 5 L = 0.2235 M
Kc=[NH3]2[N2][H2]3
Kc=( 0.2235 M)2 0.02429 M×( 0.016 M)3
The equilibrium constant, Kc=5.02×105mol2L2

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