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Question

Non-ideal gases approach ideal behavior at:

A
high temperature and high pressure
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B
high temperature and low pressure
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C
low temperature and high pressure
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D
low temperature and low pressure
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Solution

The correct option is B high temperature and low pressure
Non-ideal gases approach ideal behavior at a High temperature and low pressure.
At high temperature, V is very large. The terms aV2 and b can be neglected. The van der Waals' equation reduces to the ideal gas equation.
At low pressure, V is very large and the correction term 'b' can be neglected. At extremely low pressure, the terms aV2 can be neglected and the van der Waals' equation reduces to the ideal gas equation.

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