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Enthalpy of Neutralisation

ntwhat is the...

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ntwhat is the difference between reaction taking place in acidic medium , basic medium and neutral medium?n

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Q. Equivalent weight of

M n O_{4}^{-}

in acidic, basic, neutral medium is in the ratio is:

Q. Assertion :Sulphanilic acid migrates to anode in basic medium and to cathode in acid medium. Reason: Sulphanilic acid is a dipolar ion and exists as cation in acidic medium and as an anion in basic medium.

Q. Assertion :Carbylamine reaction takes place between

1^{o}

C H B r C l I

in basic medium. Reason: The reaction takes place by the formation of bromoiodo carbene (

: C B r I

) as intermediate

Q. How to balance a reaction taking place in basic medium by ion electron method? Explain.

E_{O_{3} | O_{2}}^{0}

(acidic medium)

= 2.07

E_{O_{3} | O_{2}}^{0}

= 1.24

E_{H_{2} O_{2} | H_{2} O}^{0}

(acidic medium)

= 1.78

E_{O_{2} | H_{2} O_{2}}^{0}

(acidic medium)

= 0.695

E_{O_{2} | H_{2} O_{2}}^{0}

= 0.076

E_{H O_{2}^{-} | O H^{-}}^{0}

= 0.878

V
Using the above data, find which of the following is incorrect?

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Enthalpy of Neutralisation

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