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Synthesis of Ethers

Nucleophilici...

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Nucleophilicity of halides in non polar, aprotic polar and polar protic solvents ?

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Q. The nucleophilicity order of halogens in polar aprotic solvent is

To synthesize the following via a single-step $S_{N} 2$ reaction starting from an alkyl halide,

S_{N} 2

reaction is carried out in the presence of polar aprotic solvent. Reason: Polar protic solvent increases the stability of carbocation due to solvation.

Q. The nucleophilicity order of halogens in polar protic solvent is :

Q. Statement-1: The order of nucleophilicity in a polar-protic solvent is:

I^{-} < B r^{-} < C l^{-} < F^{-}

Statement-2: Due to its bigger size,

I^{-}

, it is less solvated in polar-protic solvents.

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