Number average molecular mass and weight average molecular mass of synthetic polymers are related as?
For synthetic polymers, PDI > 1
This is because man-made polymers have a wide range of molecular chain lengths and weights, which increases their 'dispersity' in chain length and weight.
So, for man-made polymers, Mw>Mn
Proteins are usually mono-disperse, meaning that their chain lengths and molecular weights remain the same. So, PDI = 1.