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Question

Number of chain isomers of C6H14 is:


A

3

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B

4

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C

5

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D

6

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Solution

The correct option is C

5


There are total 5 chain isomers.
Now, as we know what is chain isomerism.

Let's try to draw isomers (chain) of C6H14

CH3CH2CH2CH2CH2CH3

n-Hexane

Now, with one substituent

CH3CH3|CHCH2CH2CH3

(2 - Methyl pentane)

Now, substituent at different carbon

CH3CH2CH|CH3CH2CH3

(3-Methyl pentane)

Now with two substituent

CH3CH3|CHCH|CH3CH3

(2, 3 - dimethyl butane)

Now at same position

CH3CH3|C|CH3CH2CH3

(2, 2 - Dimethyl butane)

Therefore, there are total 5 chain isomers.


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