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Question

Number of coordinate bonds, which are formed, when AlCl3 dimerises is/are:

A
1
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B
2
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C
3
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D
4
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Solution

The correct option is C 2
During dimerization of AlCl3, two coordinate bonds are formed. In Al2Cl6 molecule, there are 4 terminal Cl atoms and 2 bridged Cl atoms. These bridged Cl atoms donate their lone pair of electron to 2Al atoms to form 2 coordinate bonds.
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