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Question

Number of hydrogen-bonded water molecules associated in CuSO4.5H2O is :

A
One
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B
Two
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C
Three
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D
All the five
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Solution

The correct option is B One


In CuSO4.5H2O,Cu is coordinated with 4 water molecules and two more oxygen atoms from Sulphate ion.

Now fifth water molecule is hydrogen-bonded and is deeply embedded in a crystal. It is not coordinated.

Only 4 water molecules are coordinated and the fifth is the only hydrogen bonded.

Hence, option A is correct.

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