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Question

Number of lone pairs around phosphorus in PCl5,PCl+4 and PCl6− are respectively

A
0,1,2
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B
0,0,0
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C
1,2,3
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D
0,2,1
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Solution

The correct option is B 0,0,0
P atom has 5 valence electrons, PCl5, all 5 electrons involed in bonding.

PCl+4: + sign signifies loss of 1 electron, rest 4 involved in bonding.

PCl6: sign signifies gain of 1 electron, all 6 involved in bonding.

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