The correct option is C 3.011×1023
The molar mass of CO is 12g/mol+16g/mol=28g/mol.
14 g of CO corresponds to 14g28g/mol=0.5mol.
The number of molecules present in 0.5 mol of CO is 0.5mol×6.023×1023molecules/mol=3.011×1023
Thus, the number of molecules in 14g of carbon monoxide is 3.011×1023.