The correct option is A 13
Number of moles of K2Cr2O7 reduced by one mole of Sn2+ ions is 13. The balanced reaction is given below:
Cr2O2−7+14H++3Sn2+→2Cr3++7H2O+3Sn4+
From the reaction, we can see 3 moles of Sn2+ is oxidized by 1 mole of Cr2O2−7.
Hence, 1 mole of Sn2+ is oxidized by 13 mole of Cr2O2−7.