Of the following complex ions, which is diamagnetic in nature ?

[N i C l_{4}]^{2 -}

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[N i (C N)_{4}]^{2 -}

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[C u C l_{4}]^{2 -}

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[C o F_{6}]^{3 -}

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Solution

The correct option is B $[N i (C N)_{4}]^{2 -}$
${[N i (C N)_{4}]}_{4}^{2 -}$
$N i^{2 +} = 3 d^{8} 4 s^{0}$

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d p^{2}

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