Of the following statements which are true for NO2? i) Nitrogen dioxide brown liquid turns pale on cooling and becomes colourless solid ii) NO2 undergoes dimerisation to form N2O4 iii) NO2 is paramagnetic, N2O4 is diamagnetic
A
i and ii
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B
i and iii
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C
ii and iii
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D
All
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Solution
The correct option is D All NO2- paramagnetic (odd no of e−) N2O4- dimagnetic (even no of e−) 2NO2→N2O4 (dimerisation) 2NO2→N2O4 Brown liquid colourless solid