On a cold winter day, the atmospheric temperature is -θ (on Celsius scale) which is below 0∘C. A cylindrical drum of height h made of a bad conductor is completely filled with water at 0 ∘ C and is kept outside without any lid. Calculate the time taken for the whole mass of water to freeze. Thermal conductivity of ice is K, ρ is the density and latent heat of fusion is L. Neglect expansion of water on freezing
ρLh22Kθ
Suppose, the ice starts forming at time t=0 and a thickness x is formed at time t. The amount of heat flown from the water to the surrounding in the time interval t to t + dt is
ΔQ=KAθxdt
The mass of the ice formed due to the loss of this amount of heat is
dm=ΔQL=KAθxLdt
The thickness dx of ice formed in time dt is
dx=dmAρ=KθρxLdt
or, dt=ρLKθxdx
Thus, the time T taken for the whole mass of water to freeze is given by
∫T0dt=ρLKθ∫h0xdx
or, T=ρLh22Kθ