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Question

On adding a drop of barium chloride solution to an aqueous solution of sodium sulphite, white precipitate is obtained. On adding dilute hydrochloric acid to the reaction mixture, white precipitate disappears. Why?

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Solution

BaCl2+Na2SO3BaSO3(whiteppt.)+2NaCl

BaSO3+2HClBaCl2+SO2+H2O

Due to the formation of BaCl2 which is soluble in water the white ppt. disappears.

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