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Question

On analysis, a substamnce was found to contain;
C = 54. 54% H= 9.09 % O = 36.36 %
The vapour density fo the substance is 44, calculate:
(a) its empirical formula, (b) its molecular formula.

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Solution

element % At.mass Atomic ratio simple ratio
C 54.54 12 54.5412=4.55 2
H 9.09 1 9.091=9.09 4
O 36.36 16 36.3616=2.27 1


(a)So, its empirical formula =C subscript 2 H subscript 4 O
(b)emperical formula mass =44
since vapour density =44
So, molecular mass =2 × VD=88
or n=2
so molecular formula =left parenthesis c subscript 2 H subscript 4 O right parenthesis subscript 2 equals C subscript 4 H subscript 8 O subscript 2


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