The correct options are
B ZnCO3
C ZnSO3
D MgCO3
Na2CO3 is a very stable carbonate, resisting decomposition upto a very high temperature, often till its melting temperature, hence no CO2 is liberated. In case of ZnCO3 and MgCO3 being heated CO2 is liberated. In case of ZnSO3, SO2 is liberated on heating along with zinc oxide.