On compete of 2 gm methane 26575 cals heat is generated . The heat of formation of methane will be (given heat of formation of CO2 and H2O are - 97000a and - 68000 cals respectively ):
For 2gm CH4 -26575 calsFor 16gm -( 26575÷2)×16=212600Now for C + 2H2 = CH4Heat of formation of CO2 +2(heat of formation of H2O ) -heat of combustion of CH4=-97000+2(-68000)-(-212600)=-97000-136000+1212600=-20400