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Question

On electrolysis of potassium succinate solution, the hydrocarbon obtained is:

A
Ethene
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B
Ethane
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C
Ethyne
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D
All of these
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Solution

The correct option is A Ethene
Accornding to the Kolbe reaction where in this reaction the formation of decarboxylative dimerisation of two carboxylic acids. Where overall general reaction of Kolbe reaction is:
2RCOO RR +2CO2 +2e
In dicarboxylates the intramolecular bonding produces alkene.
Potassium succinate results in formation of ethene by Kolbe electrolysis.

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