a) This is a chemical change.
Heating limestone to over 900 degree C under goes thermal decomposition to produce calcium oxide and carbon dioxide.
limestone ==> quicklime + carbon dioxide
calcium carbonate ==> calcium oxide + carbon dioxide
CaCO3(s) ==> CaO(s) + CO2(g)
b) Acidic and basic solutions can be prepared by dissolving products of the above process in water.
CaO + H2O -------> Ca(OH)2 (basic solution)
Calcium oxide + water-----------> calcium hydroxide (basic solution)
CO2 + H2O ----------> H2CO3 (acidic solution)
Carbon dioxide + water --------> Carbonic acid (acidic solution)