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Question

On heating the salt with HNO3 and ammonium molybdate, formation of yellow ppt indicates the presence of AsO34 or PO34.

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Solution

On heating the salt with HNO3 and ammonium molybdate, formation of yellow ppt indicates the presence of AsO34 or PO34
Ba3(PO4)2+6HNO33Ba(NO3)2+2H3PO4
H3PO4+12(NH4)2.MoO4+21HNO3(NH4)3PO4.12MoO3+12H2O+21NH4NO3 (Ammoniumphosphomolybdate,yellowppt)
Same reaction is also given by arsenate anion.

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