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Question

On heating with bleaching powder, ethyl alcohol is converted into:

A
CH3COOH
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B
CH3CHO
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C
CH3COCH3
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D
CHCl3
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Solution

The correct option is C CHCl3
Ethyl alcohol reacts with bleaching powder to give chloroform (CHCl3). This reaction is called haloform reaction and occurs in several steps.
CaOCl2+H2OCa(OH)2+Cl2

H2O+Cl2HCl+[O]

C2H5OH+[O]CH3CHO+H2O

CH3CHO+Cl2CCl3CHO

2CCl3CHO+Ca(OH)22CHCl3+2(HCOO)Ca

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