On mixing 15.0 ml of ethyl alcohol of density 0,792gml−1 with 15 ml of pure water at 4oC, the solution is found to have a density of 0.924gml−1. The percentage contraction in volume is:
Mass of alcohol =15×0.792=11.88 g
Mass of water =15×1=15 g
Total mass =11.88+15=26.88 g
Volume of solution =mass of componentsdensity of solution
=26.880.924=29.0909 mL
Expected volume =(15+15)=30 mL
Difference =30–29.0909=0.909 mL
% Concentration in volume = differenceexpected volume×100
=0.90930×100
=3.03%