On passing a current through a molten aluminium chloride for some time produced 11.28lit of Cl2 at NTP at anode. The quantity of aluminium deposited at cathode is:
A
27grams
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B
18gram
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C
9gram
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D
36 gram
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Solution
The correct option is D 9gram 11.2lofcl2atNTP ⇒0.5moleofcl2 cl2 gives 2 moles of electer 2cl−+2e−→cl2 ∴molesofe−=0.5×2=1 Al3t+3e−→AC ∴ 1 mole of Ac requires 3 moles of e ∴ 1 mole e− reduces 13 moles of AC moleofAC=13×27=9