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Question

On reacting copper hydroxide with an excess of ammonium hydroxide and ammonium sulphate, we get a deep blue solution. The formula of the solution is :

A
[Cu(NH3)3]SO4
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B
[Cu(NH3)4]SO3
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C
[Cu(NH3)4]SO4
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D
[Cu(NH3)2]SO4
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Solution

The correct option is B [Cu(NH3)4]SO4
CuCl2+(NH4)2SO4+2NH4OH4H2O+[Cu(NH3)4]SO4
[Cu(NH3)4]SO4 is a deep blue solution and the reaction is a characteristic property of Cu2+.

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