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Solubility Product

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Question

On reaction with AgCl with ammonia solution we get a complex compound whose central atom has __________number of ligands.

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Solution

When the silver cation (Ag+) reacts with the chlorine anion (Cl-) in the presence of soluble chlorides such as hydrochloric acid, silver(I) chloride forms as a white precipitate. This precipitate is insoluble in acids such as HNO3 but dissolves in aqueous ammonia, forming a complex ion as
$A g C l + N H_{3} \to [A g (N H_{3})_{2} + C l^{-}$ .

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