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Question

On reaction with benzene, which halide is least reactive for Friedel crafts reaction?

A
Isopropyl chloride
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B
Vinyl chloride
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C
Methyl chloride
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D
Allyl chloride
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Solution

The correct option is B Vinyl chloride
Vinyl chloride do not react as it intermediate carbocation are too unstable due to presence of +ve charge on sp hybridised carbon. thus Vinyl chloride is least reactive.

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