On the basis of crystal field theory write the electron configuration for d6 in terms of t2g and eg when pairing energy is less than splitting ener

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Q. What is meant by crystal field splitting energy ? On the basis of crystal field theory, write the electronic configuration of

d^{4}

in terms of

t_{2 g}

and

e_{g}

in an octahedral field when
(i)

Δ_{0} > P

(ii)

Δ_{0} < P

Q. Electronic configuration of

[C u (N H_{3})_{6}]^{2 +}

on the basis of crystal field splitting theory is :

Q. Give the electronic configuration of the following on the basis of crystal field splitting theory.

{[C o F_{6}]}^{3 -}

and

{[C u {({N H}_{3})}_{6}]}^{2 +}

Give the electronic configuration of the following complexes on the basis of crystal field splitting theory. $[C o F_{6}]^{3 -}, [F e (C N)_{6}]^{4 -}$ and $[C u (N H_{3})_{6}]^{2 +} .$

Q. Low spin complex of

d^{6} -

cation in an octahedral field will have the following crystal field stabilization energy

(Δ_{0} =

crystal field splitting energy in an octahedral field,

P =

Electron pairing energy)

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