Vant Hoff's Equation and Effect of Temperature on Equilibrium Constant
On the basis ...
Question
On the basis of kinetic theory explain why, ammonium chloride sublimes and goes from solid state directly into vapour state.
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Solution
Ammonium chloride decomposes on heating.
NH4Cl(G)⟶NH3(g)+HCl(g)
The solid particles are heated and are filled with energy. This energy is outforced. Hence it sublines. Since, ammonium chloride has stong inter-molecular forces of attraction, it doesn't need any external source of heat for its' sublimation.