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Question

On the basis of LCAO-MO theory, the magnetic characteristics of N2 and N+2 are



A

Both diamagnetic

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B

Both paramagnetic

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C

N2 diamagnetic and N+2 paramagnetic

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D

N2 paramagnetic and N+2 dimagnetic

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Solution

The correct option is A

N2 diamagnetic and N+2 paramagnetic


N2(14):σ1s2σ 1s2 σ2s2 σ2s2 π2p2x π2p2yσ2p2z

   Diamagnetic

N+2 (13): σ1s2σ 1s2 σ2s2 σ 2s2 π2p2x π2p2y σ2p1z

   Paramagnetic


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