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Question

On the basis of standard electrode potential of redox couples given below, find out which of the following is the strongest oxidising agent.
(E0 values:Fe3+Fe2+=+0.77 V; I2(s)I=+0.54 V; Cu2+|Cu=+0.34 V; Ag+Ag=+0.80 V)

A
I2(s)
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B
Fe3+
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C
Ag+
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D
Cu2+
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Solution

The correct option is C Ag+
Higher the reduction potential, better is the oxidising agent. Now, the reduction potential decreases in the order :
Ag+Ag (+0.80 V)>Fe3+Fe2+ (+0.77 V)>I2(s)I (+0.54 V)>Cu2+Cu (+0.34 V)
Thus, Ag+ is the strongest oxidising agent.
Hence, option (d) is the correct answer.

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