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Question

On the basis of theromochemical equations( 1), (2) and (3), find out which of the algebraic relationships given in options (a) to (d) is correct
1. C(graphite)+O2(g)CO2(g); ΔrH=x kJ mol12. C(graphite)+12O2(g)CO(g);Δr H=y kJ mol13. CO(g)+12O2(g)CO2(g); ΔrH=z kJ mol1
(a) z = x + y
(b) x =y - z
(c) x =y + z
(d) y =22 - x

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Solution

(c)

The algebraic relationships of the given reaction is equation (a) -equation (b) = equation (c)
(a) C(graphite)+O2(g)CO2(g); ΔrH=xkJ mol1(b) C(graphite)+12O2(g)CO(g); ΔrH=yk J mol1CO(g)+12O2(g)CO2(g);ΔrH=yk j mol1
Hence, x- y= z or x= y+ z


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