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Question

On treatment with cold water, an element (A) reacts readily liberating a colorless, odourless gas (B) and a solution (C). Lithium is reacted with (B) yielding a solid product (D) which effervescence with water to give a strongly basic solution (E). When CO2 gas is bubbled through the solution (C), a white ppt (F) is formed but this redissolved forming solution (G) when more CO2 is passed. The precipitate (F) effervesced when moistened with conc.HCl and give deep red coloration to the Bunsen burner flame. (F) on heating with an excess of carbon at 2000oC give (H).
Solid (H) on hydrolysis gives a gas, which on passing through ammonical AgNO3 solution, yields:

A
white ppt
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B
red ppt
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C
no ppt
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D
brown ppt
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Solution

The correct option is B white ppt
The metal A is calcium. It reacts with cold water to form calcium hydroxide (C) and hydrogen gas (B) which is colorless and odorless.
Ca+2H2OCa(OH)2+H2
Lithium reacts with hydrogen gas (B) to form a solid product LiH (D).
2Li+H22LiH

olid product LiH (D) effervescence with water to give a strongly basic solution (E).
LiH+H2OLiOH+H2
When CO2 gas is bubbled through calcium hydroxide solution (C) , a white ppt of calcium carbonate (F) is formed but this redissolved forming calcium bicarbonate (G) when more CO2 is passed.
Ca(OH)2+CO2CaCO3+H2O
CaCO3+H2O+CO2Ca(HCO3)2
The precipitate (F) (calcium carbonate) effervesced when moistened with concentrated HCl and give deep red coloration to the Bunsen burner flame
CaCO3+2HClCaCl2+H2O+CO2
The deep red color is the characteristic color of calcium.
Calcium carbonate (F) on heating with excess of carbon at 2000oC give calcium carbide (H).
CaCO3+3C20000C−−−CaC2+CO+CO2
Solid (H, calcium carbide) on hydrolysis gives acetylene, which on passing through ammoniacal silver nitrate solution, yields white precipitate of silver acetylide.
CaC2+2H2OCa(OH)2+C2H2
C2H2+AgNO3+NH3C2HAg+NH4NO3

Hence, Option-A is correct.

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