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Question

On vigorous oxidation by permanganate solution (CH3)2C=CH−CH2CHO gives :

A
(CH3)2CO and OHCCH2CHO
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B
(CH3)3COH and HCHO
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C
(CH3)2CO and OHCCH2COOH
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D
(CH3)2CO and CH2(COOH)2
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Solution

The correct option is D (CH3)2CO and CH2(COOH)2
On vigorous oxidation by permangnate solution (CH3)2C=CHCH2CHO gives (CH3)2CO and CH2(COOH)2. The C=C bond is cleared and oxidised to COOH,CHO group is also oxidised to COOH.
(CH3)2C=CHCH2CHO[O]−−−−KMnO4(CH3)2CO+COOHCH2COOH
Due to vigorous oxidation the π bond breaks and oxidation takes place forming ketone and acid.

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