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Question

One faraday of charge was passed through the electrolytic cells placed in series containing solutions of Ag+,Ni2+ and Cr3+ respectively. The amount of Ag (At. mass 108),Ni (At. mass 59) and Cr (At. mass 52) deposited will be:

A
Ag=108 g,Ni=29.5 g,Cr=17.5 g
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B
Ag=108 g,Ni=59.0 g,Cr=52.0 g
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C
Ag=108 g,Ni=108.0 g,Cr=108.0 g
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D
Ag=108 g,Ni=117.5 g,Cr=166.0 g
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Solution

The correct option is C Ag=108 g,Ni=29.5 g,Cr=17.5 g
When 1 faraday of current was passed through the electrolytic cell then amount deposited will be
For Ag , w=1081 = 108 g

for Ni = w=592 = 29.5 g

for Cr = w=523 = 17.3

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