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Question

One litre of co2 is passed through red hot coke. The volume becomes 1.4 litres at same temperature and pressure. The composition of products is:

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Solution

Chemical Equation:
CO2+C2CO

According to the problem, one litre of CO2 reacts with 1 mole of Carbon to produce 2 litres of CO.
Given 1.4L is the mixtures of gases[CO+unreacted CO2].

If x litres of CO2 are reacts to give 2x litres of CO .

Total volume of mixture will be=CO2+CO
Volumes V (mixture) =V (new volume of CO2) +V(CO)=1.4 L
V(new CO2)=V(initial Volume CO2)-V(reacted CO2) =(1x) L
V(CO)=2x
So , we get
V(new volume of CO2) +V(CO)=1.4L
(1x)+2x=1.41x=1.411.4=x
X=0.4L
From, V(new CO2) =V (initial Volume CO2)-V(reacted CO2)=(1x)L
=10.4=0.6 L of CO2
Since V(CO)=2x
Volume of CO=2×0.4=0.8L of CO
Therefore, the composition of product is 0.6 litres of CO2 and 0.8 litres of CO.

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