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Question

One litre of CO2 is passed through red hot coke. The volume becomes 1.4 litres at same temperature and pressure. The composition product is:

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Solution

The reaction equation is
CO2+C2CO
IV IV 2V
Let xL of CO2 gives 2xL of CO.
Volume of CO2 left =1x
Total volume =1.4L
So,
(1x)+2x=1.4
1+x=1.4
x=0.4L
As CO=2x=2×0.4=0.8L
Volume of CO2=1.40.8=0.6L
Composition of product is 0.8L CO & 0.6L of CO2.

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