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Question

One litre of oxygen at a pressure of 1 atm and two litres of nitrogen at a pressure of 0.5 atm at the same temperature are introduced into a vessel of one litre volume. If there is no change in the temperature, then final pressure of the mixture of gases is

A
1 atm
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B
3 atm
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C
2 atm
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D
4 atm
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Solution

The correct option is C 2 atm
Given:
Volume of oxygen, V1=1 L
Pressure of oxygen, P1=1 atm
Volume of nitrogen, V2=2 L
Pressure of nitrogen, P2=0.5 atm
Volume of vessel, V=1 L
To find:
Final pressure of the mixture, P=?

We know that ideal gas equation is given by,
PV=nRT
So, number of moles of oxygen, n1=P1V1RT1............(1)
Similarly, number of moles of nitrogen, n2=P2V2RT2............(2)
Also, number of moles of mixture, n=PVRT .............(3)
Number of moles of the mixture will be equal to the sum of number of moles of oxygen and nitrogen.
From (1), (2) and (3),
PVRT=P1V1RT1+P2V2RT2
P=P1V1+P2V2V
[ given temperature is same for both gases and does not change on mixing i.e T1=T2=T ]
P=1×1+0.5×21
P=2 atm

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