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Question

One mole of a non-ideal gas undergoes a change of state :

(2.0 atm, 3.0L, 95(K)(4.0atm,5.0L,245K) with a change in internal energy, U=30.0L.atm. The change in enthalpy (H) of the process in L.atm is:

A
40.0
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B
42.3
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C
44.0
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D
None of the above
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Solution

The correct option is D 44.0
Solution:- (C) 44.0
Given:-
(2 atm ,3.0 L ,95 K)(4 atm ,5.0 L ,245 K)

Therefore,
P1=2atm,P2=4atm
V1=3L,V2=5L
T1=95KT2=245K
ΔU=30L.atm

As we know that,
ΔH=ΔU+(P2V2P1V1)
ΔH=30+(4×52×3)
ΔH=30+14=44L.atm

Hence the change in enthalpy is 44L.atm.

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