One mole of a non ideal gas undergoes a change of state (2.0atm,3.0L,98K)→(4.0atm,5.0L,245K) with a change in internal energy, ΔU=30.0Latm. The change in enthalpy ΔH of the process in L atm is:
A
40.0 L atm
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B
42.3 L atm
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C
44.0 L atm
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D
Not defined because pressure is not constant
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Solution
The correct option is C44.0 L atm H=U+PV ∴ΔH=(U2+P2V2)−(U1+P1V1) =(U2−U1)+P2V2−P1V1 =30+(4×5−2×3)=44L atm