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Question

One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass of 44u. The alkene is:

A
Ethene
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B
Propene
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C
But-1-ene
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D
But-2-ene
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Solution

The correct option is D But-2-ene
Molecular formula of an aldehyde is CnH2nO
n×12+2n×1+16=44n=2
C2H4O

The aldehyde with molecular mass 44u is CH3CHO (acetaldehyde).

Therefore the symmetrical alkene is but-2-ene.

CH3CH=CHCH3(i)O3−−−−−−(ii)Zn/H2O2CH3CHO

but-2-ene acetaldehyde

Option D is correct.

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