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Question

One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is ws and that along the dotted line path is wd, then the value close to the ratio wdws is-
(Take log11=1.04)


A
1.8
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B
4.8
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C
5.5
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D
6.2
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Solution

The correct option is A 1.8
Work done in both the paths is done by the gas as volume is expanding so work done will be negative and is given as
dw=PdV
In the P-V graph work done will be equal to area under the curve since area cannot be negative we will consider the magnitude of work done only.
Now, work done along path of solid line is reversible in nature while along the dashed line it is irreversible.

So, for irreversible, work done is equal to the sum of areas of the three rectangles i.e :

Wd=(4×1.5)+(0)(1×1)(12×2.5) = 334 Latm

For the process along the solid line (reversible) work is given as,
Ws=2.303×P1V1 logV2V1
=2.303×4×0.5× log5.50.5
=4.6× log (11) Latm

So, WdWs=334×4.6× 1og 11=1.72 (approx.)

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