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Question

One mole of an ideal gas with heat capacity at constant pressure Cp undergoes the process T=T0+αV, where T0 and α are constants, T is temperature and V is volume of the gas. The specific heat capacity of the gas as a function of its volume is: (if Cp and CV denote specific heat at constant pressure and constant volume respectively)

A
C=CP+RT0αV
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B
C=CP
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C
C=CV+RT0αV
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D
C=RT0αV
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Solution

The correct option is A C=CP+RT0αV
The specific heat is given by
C=CV+PndVdT
We have,
T=T0+αV
dTdV=0+α
dVdT=1α
Pn=RTV=RV[T0+αV]
=RTV+Rα
C=CV+(RT0V+Rα)×1α
=(CV+R)+RT0αV
C=CP+RT0αV

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