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Question


One mole of an ideal monoatomic gas is taken round cyclic process ABCA as shown in figure. Calculate the net heat absorbed by the gas in the path BC.
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A
13PoVo
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B
PoVo2
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C
PoVo
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D
2PoVo
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Solution

The correct option is B PoVo2
Work done by gas
W = area(ΔABC)
=12(3VoVo)(3PoPo)=2PoVo

Heat absorbed in path AB (isochoric)

dθAB=CVdT=CV(TfinalTinitial)

=CV(PfVfRPiViR)

=CVR(PfVfPiVi)

=32(PfVfPiVi)

=32(3PoVoPoVo)=3PoVo

Heat absorbed in path CA (isobaric)

dθCA=CPdT
=CP(TfinalTinitial)

=CP(PfVfRPiViR)

=CPR(PfVfPiVi)[CP=52RCPR=52]=52(PoVo3PoVo)=5PoVo

(heat is released)
Total heat absorbed during the process

dθ=dθAB+dθBC+dθCA

=3PoVo+dθBC+(5PoVo)

dθ=2PoVo+dθBC

Since change in internal energy is 0 i.e. dU=0

dθ=dW=2PoVo

2PoVo=2PoVo+dθBC

dθBC=4PoVo

So heat absorbed by process BC is PoVo2
Hence option B is correct.

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